Bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ3N,N′,O1)cobalt(III) nitrate monohydrate
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چکیده
منابع مشابه
2-Phenylimidazolium nitrate monohydrate
In the title hydrated mol-ecular salt, C(9)H(9)N(2) (+)·NO(3) (-)·H(2)O, the dihedral angle between the aromatic rings in the cation is 11.09 (8)°. In the crystal, the components are linked into chains propagating in [101] by N-H⋯O and O-H⋯O hydrogen bonds.
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In the title compound, [Ni(C(13)H(11)N(2)O)(H(2)O)]NO(3)·H(2)O, the Ni(II) ion is coordinated by one O atom and two N atoms of the Schiff base ligand and the O atom from a water mol-ecule, forming a slightly distorted square-planar geometry. A one-dimensional double-chain structure is formed along [001] by O⋯H-O hydrogen bonds and the Ni⋯O [2.617 (3) Å] inter-actions.
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In crystal structure of the title compound, C(5)H(6)N(3)O(2) (+)·NO(3) (-)·H(2)O, inter-molecular N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds link the cations, anions and water mol-ecules into ribbons extending in [10]. Weak inter-molecular C-H⋯O hydrogen bonds further link these ribbons into sheets parallel to (3).
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In the title compound, [Zn(C(7)H(11)O(2))(C(10)H(9)N(3))(2)]NO(3)·H(2)O, the Zn(II) atom is five-coordinated by two bidentate di-2-pyridylamine ligands and one O atom from a cyclo-hexa-necarboxy-ate anion, resulting in a ZnON(4) square-based pyramidal coordination for the metal ion with the O atom in one of the basal positions. In the crystal, the components inter-act by way of O-H⋯O, O-H⋯N and...
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In the title compound, C(10)H(8)N(3)S(+)·NO(3) (-)·H(2)O, one of the N atoms of the benzimidazole unit is protonated, unlike than that in the thia-zole group. This protonation leads to equalization of the bond angles at the two N atoms of the benzimidazole group. The benzimidazole and thia-zole systems are almost coplanar, forming a dihedral angle of 0.5 (2)°. In the crystal, the nitrate anion ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536811055851